Kinetic Resolution of (+/-)-Cyclohex-1-enylsilanols by the Sharpless Asymmetric Epoxidation

DOI: 10.1039/c39930000436

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 436 - 437 (1993)

Update date:2022-08-03

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Authors:

Yamamoto, Keiji

Kawanami, Yukio

Miyazawa, Masahiro

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Article abstract of DOI:10.1039/c39930000436

Unprecedented kinetic resolution of (+/-)-cyclohex-1-enylsilanols 1 by the Sharpless asymmetric epoxidadion has been accomplished, the rate difference between enantiomers, k_rel, being >11 to give enantiomerically pure cyclohex-1-enylcyclohexylmethylsilanol 1b in a particular case.

Full text of DOI:10.1039/c39930000436

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