Journal of the Chemical Society. Chemical communications p. 436 - 437 (1993)
Update date:2022-08-03
Topics:
Yamamoto, Keiji
Kawanami, Yukio
Miyazawa, Masahiro
Unprecedented kinetic resolution of (+/-)-cyclohex-1-enylsilanols 1 by the Sharpless asymmetric epoxidadion has been accomplished, the rate difference between enantiomers, krel, being >11 to give enantiomerically pure cyclohex-1-enylcyclohexylmethylsilanol 1b in a particular case.
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