STEREOSELECTIVE SYNTHESIS OF C-9 TO C-16 FRAGMENT OF TRIENOMYCIN BASED ON THE REGIOSELECTIVE OPENING OF γ-δ-EPOXY ACRYLATES WITH TRIMETHYLALUMINIUM

DOI: 10.1016/S0040-4039(00)60495-1

Source and publish data:

Tetrahedron Letters p. 2969 - 2972 (1993)

Update date:2022-09-26

Topics:

Authors:

Yadav, J. S.

Praveen Kumar, T. K.

Maniyan, P. P.

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Article abstract of DOI:10.1016/S0040-4039(00)60495-1

The C-9 to C-16 fragment, a key intermediate for the synthesis of a 21 membered ansamycin antibiotic, Trienomycin has been synthesized, involving Sharpless asymmetric epoxidation and the key stereoselective methylation of γ-δ-epoxy acrylates by Trimethyla

Full text of DOI:10.1016/S0040-4039(00)60495-1

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