STEREOSELECTIVE SYNTHESIS OF C-9 TO C-16 FRAGMENT OF TRIENOMYCIN BASED ON THE REGIOSELECTIVE OPENING OF γ-δ-EPOXY ACRYLATES WITH TRIMETHYLALUMINIUM

DOI: 10.1016/S0040-4039(00)60495-1

Source and publish data:

Tetrahedron Letters p. 2969 - 2972 (1993)

Update date:2022-09-26

Topics:

Authors:

Yadav, J. S.

Praveen Kumar, T. K.

Maniyan, P. P.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4039(00)60495-1

The C-9 to C-16 fragment, a key intermediate for the synthesis of a 21 membered ansamycin antibiotic, Trienomycin has been synthesized, involving Sharpless asymmetric epoxidation and the key stereoselective methylation of γ-δ-epoxy acrylates by Trimethyla

Full text of DOI:10.1016/S0040-4039(00)60495-1

Products guided by the article

Product name:(E)-3-[(2S,3S)-3-(2-Benzyloxy-ethyl)-oxiranyl]-acrylic acid ethyl ester

Cas No:149916-83-6

R&D Labs maybe for 149916-83-6

Shenyang Xingzhenghe Chemical Co., Ltd.

Contact:024-23509232

Address:No. 33, Naner Road, Heping Dist.
Shanghai doly chemical Co.,Ltd

Contact:+86-21-34716221

Address:No.328,WuHe Roard,MinHang,ShangHai China
Zhejiang Linhai Xinhua Chemicals Factory

Contact:0086-13661858911

Address:Xunqiao Development Zone, Linhai, Zhejiang, China
zhuzhou zhongle chemical co. ltd.

Contact:+86-0731 28228409

Address:Zhuzhou, Hunan, China
Yurui(Shanghai)Chemical Co.,Ltd

Contact:0086 21-50456736

Address:No.3188 Xiupu Road,Shanghai

Relevant to this article

Total syntheses of (2S)-antafumicins A and B.

Doi:10.1271/bbb.58.1627
(1994)
The Use of Chemical Probes To Differentiate between Polar and SET-Hydrogen Atom Abstraction Pathways Involved in the Reduction Reaction Promoted by an 8-Al-4 Anion

Doi:10.1021/jo00074a014
(1993)
Synthesis and solvent effects on the conformation of hymenistatin 1

Doi:10.1002/hlca.19930760422
(1993)
(2E)-5-[3-[(phenylsulfonyl)amino]phenyl]pent-2-en-4-ynohydroxamic acid and its derivatives as novel and potent inhibitors of ras transformation

Doi:10.1021/jm960174k
(1996)
Unsymmetrical pincer CNN palladium complex of 7-ferrocenylmethyl-3-methyl-3,7-diazabicyclo[3.3.1]nonane

Doi:10.1016/j.jorganchem.2017.06.009
(2017)
Glycosidase-catalysed synthesis of glycosides by an improved procedure for reverse hydrolysis: Application to the chemoenzymatic synthesis of galactopyranosyl-(1 → 4)-O-α-galactopyranoside derivatives

Doi:10.1016/0957-4166(96)00238-8
(1996)

Article Doi