Enantiocontrolled Synthesis of Optically Pure 5-Trimethylsilyl- and 5-Tributylstannyl-cyclohex-2-enones

DOI: 10.1039/c39930000788

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Journal of the Chemical Society. Chemical communications p. 788 - 789 (1993)

Update date:2022-09-26

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Authors:

Takano, Seiichi

Higashi, Yasuhiro

Kamikubo, Takashi

Moriya, Minoru

Ogasawara, Kunio

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Article abstract of DOI:10.1039/c39930000788

Optically pure 5-trimethylsilyl- and 5-tributylstannyl-cyclohex-2-enones have been prepared efficiently in an enantiocontrolled manner starting from the common chiral precursor by employing a novel palladium-mediated elimination reaction as the key step.

Full text of DOI:10.1039/c39930000788

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