Catalytic Asymmetric Addition of Polyfunctional Dialkylzincs to β-Stannylated and β-Silylated Unsaturated Aldehydes

DOI: 10.1021/jo00094a027

Source and publish data:

Journal of Organic Chemistry p. 4143 - 4153 (1994)

Update date:2022-07-30

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Authors:

Ostwald, Roswitha

Chavant, Pierre-Yves

Stadtmueller, Heinz

Knochel, Paul

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Article abstract of DOI:10.1021/jo00094a027

The addition of functionalized dialkylzincs to readily available β-stannylated or β-silylated unsaturated aldehydes in the presence of a catalytic amount of (1R,2R)-1,2-bis(trifluorosulfonamido)cyclohexane (8 mol percent) provides chiral allylic alcohols

Full text of DOI:10.1021/jo00094a027

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