International Journal of Chemical Kinetics p. 334 - 353 (2003)
Update date:2022-08-04
Topics:
Orlando, John J.
Tyndall, Geoffrey S.
Apel, Eric C.
Riemer, Daniel D.
Paulson, Suzanne E.
The rate coefficients and mechanisms of the reaction of Cl-atoms with a series of unsaturated hydrocarbons under atmospheric conditions were studied. It was observed the product yielded from both trans-2-butene and 1-butene were found to be oxygen dependent. The results showed that the variation of the product yielded with O2 in the case of 1-butene resulted from competitive reaction pathways for the two β-chlorobutoxy radicals involved in the oxidation.
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