Bull. Russ. Acad. Sci. Div. Chem. Sci. (Engl. Transl.) p. 2189 - 2192 (1992)
Update date:2022-08-04
Topics:
Kapustina, N.I.
Nikishin, G.I.
The main product of the reaction of 1-methylcyclobutanol with Pb(OAc)4 in benzene is 1-phenyl-4-pentanone; the use of Mn(OAc)3 in acetic acid gives a mixture of 2,9-decanedione and methyl propyl ketone; 1-(chloro-, bromo-, thiocyano-, or ccyano)-4-pentanone is formed in the presence of the systems Pb(OAc)4-metal halide or Mn(OAc)3-metal halide. Keywords: oxidation, 1-methylcyclobutanol, lead tetraacetate, manganese triacetate, β-cleavage.
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