A novel synthesis of cyanoalkynes via iodide-catalyzed cyanation of terminal acetylenes with cuprous cyanide

DOI: 10.1016/S0040-4039(00)73812-3

Source and publish data:

Tetrahedron Letters p. 5911 - 5914 (1993)

Update date:2022-09-26

Topics:

Authors:

Luo, Fen-Tair

Wang, Ren-Tzong

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4039(00)73812-3

Cyanoalkynes were synthesized in fair to good yields from terminal acetylenes and cuprous cyanide in the presence of trimethylsilyl chloride, water, catalytic amount of sodium iodide, and CH₃CN in DMSO at 50°C.

Full text of DOI:10.1016/S0040-4039(00)73812-3

Products guided by the article

Product name:Benzoic acid, 2-(cyanoethynyl)-, methyl ester

Cas No:151589-37-6

R&D Labs maybe for 151589-37-6

Taizhou Sunny Chemical Co.,Ltd

Contact:+86-523-86920899 +86-13951172783

Address:No.11 Xingyuang road, Gaoyong Chemical Industry Park, Gaogang Jiangsu China
Zhenjiang Huayu I/E Co.,LTD

Contact:86-511-85210668 0511-85210668, 85210818, 85210898

Address:Yihai Garden E-902,NO.99 Daxi RD., Zhenjiang Jiiangsu ,China
Weifang Arylchem Chemical Co., LTD

Contact:86-536-5217866

Address:Development Zone, Shouguang, Shandong Province
Binzhou Holly Pharmaceutical Co.,Ltd.

Contact:74517

Address:No.15 Dapu Road,Huangpu District Shanghai,P.R.China
Jiangsu Hualun Chemical Industry Co., Ltd

website:http://www.hualunchem.com

Contact:+86-0514-86464168 86507985

Address:39# Middle Renmin Road, Dinghuo Town

Relevant to this article

Electrochemically induced S(RN)1 reactions: Selective substitutions at 1,4-dichlorobenzene

Doi:10.1055/s-1993-25942
(1993)
Intramolecular Nucleophilic Acyl Substitution Reactions of Halo-Substituted Esters and Lactones. New Applications of Organosamarium Reagents

Doi:10.1021/jo00077a053
(1993)
Imidoyl dichlorides as new reagents for the rapid formation of 2-aminobenzimidazoles and related azoles

Doi:10.1016/j.tetlet.2015.09.076
(2015)
Stereocontrol in asymmetric S_E' reactions of γ-substituted α,β-unsaturated aldehydes

Doi:10.1021/ol403351x
(2014)
Studies of the synthesis of providencin: Construction and assembly of two major subunits

Doi:10.1021/jo402485h
(2014)
Tetrahydro-pyrrolo-[2,3-b]indole-1,2,8-tricarboxylic acid ester in the enantiospecific preparation of α-methyltryptophan: Application in the preparation of carbon-14 labeled PD 145942 and PD 154075

Doi:10.1002/(SICI)1099-1344(199712)39:12<1019::AID-JLCR43>3.0.CO;2-T
(1997)

Article Doi