Tetrahedron p. 6463 - 6472 (1993)
Update date:2022-08-03
Topics: Oxidation Characterization Derivatization Deprotection Purification Protection of Functional Groups
De Bie, Joannes F. M.
Peperzak, Rob M.
Daenen, Marian J.
Scheeren, Hans W.
(+/-)-Daunomycinone and (+/-)-4-demethoxydaunomycinone have been synthesized via two successive Diels-Alder reactions from naphthazarin. Key steps for the construction of the A-ring of the anthracyclinone are the Diels-Alder reaction of the BCD fragments
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