Tetrahedron Letters p. 5621 - 5622 (1993)
Update date:2022-07-30
Topics:
Aitken
Herion
Janosi
Raut
Seth
Shannon
Smith
Flash vacuum pyrolysis of a series of 1,2,4-trioxo-3-triphenylphosphoranylidene-butane derivatives, formed by acylation of β-oxo-phosphorus ylides with α-oxo-acid chlorides, results in extrusion of Ph3PO exclusively across the 2,3-position to give diacylalkynes.
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Doi:10.1016/0040-4020(70)85021-9
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(1993)Doi:10.1021/jm00076a029
(1993)Doi:10.1016/j.bmc.2008.09.011
(2008)Doi:10.1021/jo5015239
(2014)Doi:10.1021/ja903732v
(2009)
