Generation and alkylation of α-lithio-Se,O-heteroacetals, and stereoselective cyclization of olefinic Se,O-heteroacetals

DOI: 10.1248/cpb.41.1160

Source and publish data:

Chemical and Pharmaceutical Bulletin p. 1160 - 1162 (1993)

Update date:2022-09-26

Topics:

Authors:

Yoshimatsu

Fujimoto

Shimizu Shimizu

Hori Hori

Kataoka Kataoka

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Article abstract of DOI:10.1248/cpb.41.1160

Generation of α-lithio-Se,O-heteroacetals was accomplished by direct deprotonation of O-methoxyethylselenoacetals with lithium 2,2,6,6- tetramethylpiperidide. Alkylation of the α-lithioheteroacetals smoothly proceeded to give the products 6 and 7. Olefini

Full text of DOI:10.1248/cpb.41.1160

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