Novel Srereocontrolled Syntheses of Exocyclic γ-Oxovinyltrimethylsilanes. A Potential Route for Stereodefined Exocyclic Tetrasubstituted Alkenes

DOI: 10.1039/c39930001365

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 1365 - 1367 (1993)

Update date:2022-08-04

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Authors:

Nakatani, Kazuhiko

Izawa, Tomoko

Odagaki, Yoshihiko

Isoe, Sachihiko

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Article abstract of DOI:10.1039/c39930001365

The course of the dehydration of α-hydroxy-γ-oxotrimethylsilanes is highly dependent on the conditions to produce stereoselectively (Z)- and (E)-γ-oxovinyltrimethylsilanes, which are potential precursors for preparation of stereodefined exocyclic tetrasub

Full text of DOI:10.1039/c39930001365

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