Chemistry of Heterocyclic Compounds p. 658 - 663 (1980)
Update date:2022-09-26
Topics:
Buzilova, S. R.
Shul'gina, V. M.
Gareev, G. A.
Vereshchagin, L. I.
2-Alkyl-5-ethynyltetrazoles were synthesized.It is shown that ethynyltetrazoles have a triple bond with increased electrophilicity.They readily add aliphatic alcohols and amines and undergo aminomethylation, the Iotsich reaction, oxidative dimerization, and the cycloaddition of azides. 1-Phenyl-3-tetrazolyl-2-propyne, which has the properties of α-acetylenic ketones, was obtained by selective oxidation of tetrazolylethynylcarbinol.
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