Tetrahedron p. 8179 - 8194 (1993)
Update date:2022-07-31
Topics:
Orlek, Barry S.
Sammes, Peter G.
Weller, David J.
Use of conformational constraints, induced by different ortho-substituents in 1-allyloxy-2-(substituted)methylbenzenes, where the substituent is a 1,3-dipole such as the azide or 3-oxidopyridinium group, can be employed to accelerate the 1,3-dipolar cycloaddition reaction. In this manner cycloadditions that otherwise do not proceed can be forced to react.
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