Electrochemical generation and reactivity of bis(triphenylphosphine)platinum(0): An electrosynthesis of platinum-acetylene complexes

DOI: 10.1021/om00137a038

Source and publish data:

Organometallics p. 1264 - 1266 (1986)

Update date:2022-09-26

Topics: Reactivity Electrosynthesis

Authors:

Davies, Julian A.

Eagle, Cassandra T.

Otis, Deborah E.

Venkataraman, Uma

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Article abstract of DOI:10.1021/om00137a038

Controlled potential bulk reductive electrolysis of cis-[PtCl₂(PPh₃)₂] results in the generation of [Pt(PPh₃)₂] in solution. This 2-coordinate, 14-electron compound is efficiently trapped by acetylene

Full text of DOI:10.1021/om00137a038

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