A Novel Route to Stable Silacyclopropenes - First Synthesis of Silacyclopropenes bearing Vinylic Hydrogen

DOI: 10.1016/0040-4039(93)88099-5

Source and publish data:

Tetrahedron Letters p. 6541 - 6544 (1993)

Update date:2022-08-04

Topics:

Authors:

Belzner, Johannes

Ihmels, Heiko

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Article abstract of DOI:10.1016/0040-4039(93)88099-5

Starting from easily accessible cyclotrisilane 1, stable silacyclopropenes 3a - e are obtained in high yield.Their NMR spectroscopic data indicate appreciable charge delocalization throughout the three membered ring system.

Full text of DOI:10.1016/0040-4039(93)88099-5

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