A Novel Route to Stable Silacyclopropenes - First Synthesis of Silacyclopropenes bearing Vinylic Hydrogen

DOI: 10.1016/0040-4039(93)88099-5

Source and publish data:

Tetrahedron Letters p. 6541 - 6544 (1993)

Update date:2022-08-04

Topics:

Authors:

Belzner, Johannes

Ihmels, Heiko

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/0040-4039(93)88099-5

Starting from easily accessible cyclotrisilane 1, stable silacyclopropenes 3a - e are obtained in high yield.Their NMR spectroscopic data indicate appreciable charge delocalization throughout the three membered ring system.

Full text of DOI:10.1016/0040-4039(93)88099-5

Products guided by the article

Product name:{2-[1-(2-Dimethylaminomethyl-phenyl)-2-propyl-1H-siliren-1-yl]-benzyl}-dimethyl-amine

Cas No:153123-21-8

R&D Labs maybe for 153123-21-8

TAIXING BEST NEW MATERIALS CO., LTD

Contact:0523-87998158;

Address:No.18 Zhonggang Road，Taixing City ，Jiangsu , China
Yancheng Smiling Imp & Exp Co., Ltd.

Contact:+86-515-83173586

Address:Rm1207, BLD#03, Phoenix Plaza, Juheng Road, Yancheng, Jiangsu, P.R. China
Tianjin Derchemist Sci-Tech Co., Ltd.

website:http://www.derchemist.com

Contact:+86-22-58627059

Address:Xinmao Science and Technology Park，Huayuan Industrial Park
Second Pharma Co., Ltd

Contact:+86-575-82733999 0575-82732999

Address:hangzhou gulf fine chemical zone,shangyu city,zhejiang province
Zhejiang Medicines & Health Products Import & Export Co.,Ltd.

Contact:+86-571-56970720/0571-28935815

Address:ZMC BUILDING, 101-2, N. ZHONGSHAN ROAD.

Relevant to this article

Excellent selectivity for actinides with a tetradentate 2,9-diamide-1,10-phenanthroline ligand in highly acidic solution: A hard-soft donor combined strategy

Doi:10.1021/ic402784c
(2014)
Palladium(II) complexes of N2O2 and N2S2 ligands: Syntheses and X-ray crystal structures

Doi:10.1007/BF01185542
(1993)
Solvent-induced helical assembly and reversible chiroptical switching of chiral cyclic-dipeptide-functionalized naphthalenediimides

Doi:10.1002/chem.201303123
(2013)
Doi:10.1021/jo01266a114
(1968)
Hysteretic spin crossover in iron(ii) complexes of a new pyridine-triazole-pyrazine ligand is tuned by choice of NCE co-ligand

Doi:10.1039/c3cc43922d
(2014)
A facile synthesis of 5,5-dideutero-4-dimethyl(phenyl)silyl-6-undecyl- tetrahydropyran-2-one as a deuterium labeled synthon for (-)-tetrahydrolipstatin and (+)-δ-hexadecanolide

Doi:10.1002/jlcr.3081
(2013)

Article Doi