Triethylborane Induced Intramolecular Hydrogermylation of Homoallylic Alcohols and Homopropargylic Alcohols

DOI: 10.1246/cl.1993.1751

Source and publish data:

Chemistry Letters p. 1751 - 1754 (1993)

Update date:2022-07-30

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Authors:

Taniguchi, Masahiko

Oshima, Koichiro

Utimoto, Kiitiro

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Article abstract of DOI:10.1246/cl.1993.1751

Whereas platinum-catalyzed hydrogermylation of 3-hexenoxydipropylgermane provided five-membered ring product (5-propyl-1-germa-2-oxacyclopentane) as a main product, triethylborane induced radical cyclization gave six-membered ring product (6-ethyl-1-germa-2-oxacyclohexane) selectively.

Full text of DOI:10.1246/cl.1993.1751

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