Journal of the American Chemical Society p. 558 - 561 (1994)
Update date:2022-09-26
Topics:
Henderson, Ian
Sharpless, K. Barry
Wong, Chi-Huey
A new strategy is described for the asymmetric synthesis of carbohydrate derivatives via the tandem use of the osmium-catalyzed asymmetric dihydroxylation (AD) and aldolase-catalyzed aldol addition reactions. Both D- and L-forms of fructose, 6-deoxy-galacto-2-heptulose, and 6-phenyl-galacto-2-hexulose were synthesized to illustrate this methodology.
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