STEREOSPECIFIC INTRAMOLECULAR FORMYL TRANSFER VIA RADICAL CYCLIZATION-FRAGMENTATION: PREPARATION OF ALKYL 2-DEOXY-2α-FORMYLGLUCOPYRANOSIDES AND SIMILAR COMPOUNDS

DOI: 10.1016/S0040-4039(00)73722-1

Source and publish data:

Tetrahedron Letters p. 6247 - 6250 (1993)

Update date:2022-09-26

Topics:

Authors:

Jung, Michael E.

Choe, S. W. Tina

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4039(00)73722-1

An efficient synthesis of alkyl-2-deoxy-2α-formylglucopyranosides is described.The key step involves a novel stereospecific intramolecular formyl transfer via a radical cyclization-fragmentation process in good yield.

Full text of DOI:10.1016/S0040-4039(00)73722-1

Products guided by the article

Product name:benzyl 3,4,6-tri-O-benzyl-2-deoxy-2-C-formyl-α-D-glucopyranoside

Cas No:153289-66-8

R&D Labs maybe for 153289-66-8

Melone Pharmaceutical Co., ltd

Contact:+86-411 82593920, 82593631

Address:No 232, JInma Roda, Development Zone, Dalian, China
Beijing Chemdow Co., Ltd

website:http://www.chemdow.com

Contact:0086-10-82435335

Address:Room 401,Unit 3,4th Floor,Shangdijiayuan,Shangdi East Road, Haidian District,Beijing
TLS PHARMACEUTICAL CO.,LTD

Contact:0833-5590788/5590338/5590055

Address:Victory in the town of Red Star Village,Mount Emei City,industrial concentration area storage processing logistics parkpark
Sarchem Laboratories, Inc.

Contact:732.938.2777

Address:5012 Industrial Road Farmingdale, NJ 07727
TIANJIN NORTH JINHENG CHEMICAL PLANT.

Contact:0086-22-59952083

Address:DongShigu Country In JiXian TianJin China

Relevant to this article

Diastereo- and regioselective addition of thioamide dianions to imines and aziridines: Synthesis of N-thioacyl-1,2-diamines and N-thioacyl-1,3-diamines

Doi:10.1002/chem.201203470
(2013)
New derivatives of dehydroabietic acid target planktonic and biofilm bacteria in S taphylococcus aureus and effectively disrupt bacterial membrane integrity

Doi:10.1016/j.ejmech.2015.07.038
(2015)
The total synthesis of antrimycin D(v); II: Synthesis of tetrahydropyridazinecarboxylic acid and its incorporation into peptides

Doi:10.1055/s-1993-25947
(1993)
"One-pot" reductive lactone alkylation provides a concise asymmetric synthesis of chiral isoprenoid targets

Doi:10.1021/ol401801g
(2013)
Cine-substitution reactions of metallabenzenes: An experimental and computational study

Doi:10.1002/chem.201301398
(2013)
Halonium ion mediated synthesis of 2-halomethylene-3-oxoketoxime derivatives from isoxazoline N -oxides

Doi:10.1021/jo401283x
(2013)

Article Doi