STEREOSPECIFIC INTRAMOLECULAR FORMYL TRANSFER VIA RADICAL CYCLIZATION-FRAGMENTATION: PREPARATION OF ALKYL 2-DEOXY-2α-FORMYLGLUCOPYRANOSIDES AND SIMILAR COMPOUNDS

DOI: 10.1016/S0040-4039(00)73722-1

Source and publish data:

Tetrahedron Letters p. 6247 - 6250 (1993)

Update date:2022-09-26

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Authors:

Jung, Michael E.

Choe, S. W. Tina

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Article abstract of DOI:10.1016/S0040-4039(00)73722-1

An efficient synthesis of alkyl-2-deoxy-2α-formylglucopyranosides is described.The key step involves a novel stereospecific intramolecular formyl transfer via a radical cyclization-fragmentation process in good yield.

Full text of DOI:10.1016/S0040-4039(00)73722-1

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