Helvetica Chimica Acta p. 2329 - 2337 (1993)
Update date:2022-09-26
Topics:
Oppolzer, Wolfgang
Fuerstner, Alois
Octadienyl carbonates 5 provide cyclic 1,4-dienes 6 when treated with RhI complexes (1-10 mol-percent) at 80 deg C.Similar cyclization of cyclohexenyl acetate 8 affords cis-fused hexahydroindene 9.Analogues ring closures of nonadiene carbonate 10 yield preferably the cis-divinylpyrrolidine 11 with RhI catalysis but the trans-isomer 12 when catalyzed by Pd0.Azaoctadienyl carbonate 5a undergoes elimination with
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(1962)Doi:10.1039/CT9007700150
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(2014)Doi:10.14233/ajchem.2013.14878
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(1963)Doi:10.1007/BF00758052
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