Journal of the American Chemical Society p. 1292 - 1295 (2014)
Update date:2022-09-26
Topics:
Samuel, Prinson P.
Li, Yan
Roesky, Herbert W.
Chevelkov, Veniamin
Lange, Adam
Burkhardt, Anja
Dittrich, Birger
Trifluorinated germanium anions attracted attention of theoretical chemists already in the late 1990s to predict their physical and chemical properties. However these species were not synthesized in the laboratory, although substantial evidence for their existence was obtained from the mass spectrometry of GeF4. The present study shows that controlled fluorination of LMNMe2 (L = PhC(NtBu)2, M = Ge, Sn) using HF·pyridine in toluene leads to the formation of [LH2] +[MF3]- under elimination of HNMe2. The products contain the trifluorinated Ge(II) and Sn(II) anionic species which are stabilized by interionic H···F bonds. The new compounds were characterized by single crystal X-ray structural analysis, NMR spectroscopy, and elemental analysis.
View MoreZhangjiagang Methese Composite Material Co.,
Contact:0512-85428658
Address:Shazhou Lake Technological Innovation Park,Zhangjiagang City,Jiangsu Province,China
Taizhou Huading Chemical Co.,Ltd(expird)
Contact:+86-576-88583898
Address:Economic&Technology development zone,Taizhou City,Zhejiang Province,China
WUXI HONOR SHINE CHEMICAL CO.,LTD
Contact:+86-510-83593312
Address:No.1699 Huishan avenue,Huishan district,Wuxi ,Jiangsu,China,214177.(Wuxi Huishan Ecomonic Develop Zone )
Fuxin Jintelai Fluorin Chemical Co., Ltd.
Contact:+86-0418-8229599
Address:, 7th Huagong Road, Fluorine industry development zone (Yimatu Town,Fumeng County),Fuxin City, Liaoning Province, China
Quhua Zhongxing Refrigeration Technology Co.,Ltd.
Contact:+86-5708886618
Address:318 Bulding 2, No.866 Quhua Rd.,Kecheng District
Doi:10.1039/c3cc42165a
(2014)Doi:10.1080/07328319308016200
(1993)Doi:10.1016/0022-328X(93)80465-N
(1993)Doi:10.1021/jm00028a016
(1994)Doi:10.1080/15257779508014650
(1995)Doi:10.1021/acs.organomet.8b00538
(2019)