One-Pot Stereospecific Synthesis of 8a-Hydroxy- and 8a-Alkoxy-2,2,8-trisubstituted-3-oxoindolizidines. Mechanistic Studies on the Elaboration of the 8a-Substituted Indolizidine Ring

DOI: 10.1016/S0040-4020(01)81910-4

Source and publish data:

Tetrahedron p. 8911 - 8918 (1993)

Update date:2022-07-29

Topics:

Authors:

Dominguez, Maria Jose

Gracia-Lopez, Maria Teresa

Gonzalez-Muniz, Rosario

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Article abstract of DOI:10.1016/S0040-4020(01)81910-4

Stereospecific solvent-dependent synthesis of 8a(R)-alkoxy-8(S)-tert-butyloxycarbonyl-amino-2(S)-benzyl-3-oxoindolizidine-2-carboxylic acid or the corresponding methyl 8a(S)-hydroxy-2-carboxylate derivative, by hydrogenation of a conveniently protected α-

Full text of DOI:10.1016/S0040-4020(01)81910-4

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