Silver-catalyzed decarboxylative homocoupling reaction for the construction of tetrafluoroethylene-bridging aromatic compounds

DOI: 10.1080/00397911.2019.1651865

Source and publish data:

Synthetic Communications p. 2961 - 2970 (2019)

Update date:2022-09-26

Topics:

Authors:

Wang, Yong

Zhao, Huaxin

Xie, Xiaojuan

Jiang, Haizhen

Deng, Hongmei

Hao, Jian

Wan, Wen

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Article abstract of DOI:10.1080/00397911.2019.1651865

The Ag(I)-catalyzed decarboxylative homocoupling from the difluoroacetate has been developed to the synthesis of symmetric CF₂–CF₂ containing dimers. This radical dimerization overpasses the prefunctionalization of the substrate and provides a direct and efficient method for construction of tetrafluoroethylene bridge-linked homodimers.

Full text of DOI:10.1080/00397911.2019.1651865

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