
Tetrahedron p. 5193 - 5206 (1995)
Update date:2022-08-02
Topics:
Baldwin, Jack E.
Adlington, Robert M.
Mitchell, Mark B.
A stereocontrolled enantiospecific synthesis of the revised structure of anticapsin (3) is described. The carbonyl group of anticapsin has also been observed to be markedly electrophilic, showing a high propensity for hydration and enolisation. A possible role for the hydrated form of anticapsin during the inhibition of glucosamine synthetase is proposed.
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