Regio- and Enantioselective Catalytic Epoxidation of Conjugated Polyenes. Formal Synthesis of LTA4 Methyl Ester

DOI: 10.1021/jo00077a001

Source and publish data:

Journal of Organic Chemistry p. 6939 - 6941 (1993)

Update date:2022-09-26

Topics:

Authors:

Chang, Sukbok

Lee, Nam Ho

Jacobsen, Eric N.

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Article abstract of DOI:10.1021/jo00077a001

The (salen)Mn(III)-catalyzed asymmetric epoxidation reaction exhibits regioselectivity for attack at cis double bonds of conjugated dienes to afford enantiomerically enriched trans-vinyl epoxides as the major products.

Full text of DOI:10.1021/jo00077a001

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