Tetrahedron p. 11253 - 11262 (1993)
Update date:2022-09-26
Topics:
Crozet
Vanelle
Jentzer
Donini
Maldonado
The C-alkylation reaction of three reductive alkylating agents prepared from 2-methylanthraquinone by 2-nitropropane anion is shown to proceed by the S(RN)1 mechanism. The S(RN)1 mechanism is confirmed by the leaving group effect and the inhibitory effect of dioxygen, p-dinitrobenzene, cupric chloride and di-tert-butylnitroxide. This reaction can be extended to 1-methyl-3-nitropyrolidin-2-one anion.
View MoreZHIJIANG ZENVA SINO COMMERCE AND TRADE CO., LTD.
website:http://www.zenvasino.com
Contact:+86-138-72658998
Address:Shibeishan Road,Zhijiang, Hubei, China
Contact:+86-570-4336358
Address:No.87 Building,Tianqian,Sidu Town
Chengdu D-Innovation Pharmaceutical Co., Ltd
Contact:86-28-85105536
Address:1001, B6, No.88 Keyuan South Road, Chengdu Hi-Tech Zone
Qingzhou Baibang import and export co.,Ltd
Contact:+86-536-3265899
Address:No.338, Tuoshan Road
Zhejiang Linhai Xinhua Chemicals Factory
Contact:0086-13661858911
Address:Xunqiao Development Zone, Linhai, Zhejiang, China
Doi:10.1135/cccc19940222
(1994)Doi:10.1016/S0040-4020(01)80818-8
(1994)Doi:10.1002/bkcs.10283
(2015)Doi:10.1016/S0040-4020(01)80181-2
(1993)Doi:10.1016/j.tet.2013.12.073
(2014)Doi:10.3390/molecules181113654
(2013)
