Journal of Organometallic Chemistry p. 269 - 278 (1997)
Update date:2022-07-29
Topics:
Courtois
Miginiac
We describe a convenient pathway to prepare primary benzylic diamines with allylic or propargylic groups in α- and α′-positions, by use of the regiospecific reaction between organometallics (M = Zn, Al, Mg) prepared from allylic or propargylic bromides and the bis-N-trimethylsilylimines resulting from an aromatic 1,3-or 1,4-dialdehyde.
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