Preparation and utilization of chiral dihydropyridines. Synthesis of chiral indoloquinolizines and benzoquinolizines

DOI: 10.1021/jo00086a045

Source and publish data:

Journal of Organic Chemistry p. 1877 - 1888 (1994)

Update date:2022-07-29

Topics:

Authors:

Mangeney

Gosmini Gosmini

Raussou Raussou

Commercon

Alexakis

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Article abstract of DOI:10.1021/jo00086a045

An asymmetric synthesis of 3-formyl-1,4-dihydropyridines is described that entails the addition of organocopper reagents to activated 3- imidazolidinylpyridine, prepared with chiral diamines. The activator can be a chloroformate or an acid chloride. The m

Full text of DOI:10.1021/jo00086a045

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Product name:(R)-1-[2-(3,4-Dimethoxy-phenyl)-ethyl]-3-((4S,5S)-1,3-dimethyl-4,5-diphenyl-imidazolidin-2-yl)-4-methyl-1,4-dihydro-pyridine

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