Stereoselective Synthesis of (+/-)-Veadeiroic Acid and (+/-)-Veadeirol by Cyclisation of a 2-(2-Arylethyl)-1,3,3-trimethylcyclohexyl Cation: Mechanism and Stereochemistry of Related Cycloalkylation Reactions

DOI: 10.1039/P19930002223

Source and publish data:

Journal of the Chemical Society. Perkin transactions I p. 2223 - 2228 (1993)

Update date:2022-08-03

Topics:

Authors:

Saha, Arabinda

Nasipuri, Dhanonjoy

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Article abstract of DOI:10.1039/P19930002223

(+/-)-Veadeiroic acid 1 and (+/-)-veadeirol 2, two new cleistanthoid diterpenes, have been synthesized by stereoselective cyclization of the carbocation 5 generated from the cyclohexanol 26.The latter is prepared from 2-ethyl-3-formylbenzoic acid (with CO

Full text of DOI:10.1039/P19930002223

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