A Facile Entry to Macrocyclic Disulfides: An Efficient Synthesis of Redox-Switched Crown Ethers

DOI: 10.1021/jo00085a025

Source and publish data:

Journal of Organic Chemistry p. 1354 - 1357 (1994)

Update date:2022-08-04

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Authors:

Ramesha, A. R.

Chandrasekaran, Srinivasan

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Article abstract of DOI:10.1021/jo00085a025

An interesting sulfur transfer reaction with benzyltriethylammonium tetrathiomolybdate has been used efficiently for the synthesis of macrocyclic disulfides.This methodology has been extended to a high-yield synthesis of "redox-switched" crown ethers which have potential application for selective ion transport across liquid membranes.

Full text of DOI:10.1021/jo00085a025

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