A Convenient Synthesis of Optically Pure Dimethyl 1,1'-Binaphthalene-2,2'-dicarboxylate from 1,1'-Binaphthalene-2,2'-diol

DOI: 10.1016/0040-4039(93)85022-O

Source and publish data:

Tetrahedron Letters p. 1615 - 1616 (1993)

Update date:2022-08-02

Topics:

Authors:

Ohta, Tetsuo

Ito, Masata

Inagaki, Kohji

Takaya, Hidemasa

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Article abstract of DOI:10.1016/0040-4039(93)85022-O

Optically pure dimethyl 1,1'-binaphthalene-2,2'-dicarboxylate has been prepared by methoxycarbonylation of ditriflate of 1,1'-binaphthalene-2,2'-diol catalyzed by Pd(OAc)2-dppp-N,N-diisopropylethylamine in the presence of methanol under CO atmosphere in 83percent yield.

Full text of DOI:10.1016/0040-4039(93)85022-O

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