Chemistry Letters p. 21 - 22 (1994)
Update date:2022-07-29
Topics:
Hirai, Yoshiro
Nagatsu, Mayumi
The palladium-catalyzed cyclization of the optically active urethan <(-)-1>, which was obtained by enzymatic resolution of the racemic alcohol (1), gave the piperidine 6.This reaction affords highly efficient intramolecular chirality transfer.Compound 6 was converted into (+)-coniine and 2-hydroxymethylpiperidine.
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(2014)
