Stereospecific reactions of the "M(C6F5)2" (M = Pd or Pt) synthons towards cis-dithiolato complexes

Article abstract of DOI:10.1016/0022-328X(93)80283-H

Complexes of the general formula cis- (M=Ni, Pd, or Pt; L2=dppm , dppe <1,2-bis(diphenylphosphino)ethane>, or 2PPh3) were synthesized by the reaction (1 : 2) between the corresponding cis- and Tl(SC6F5).When treated with cis- (M=Pd or Pt; THF=OC4H8) they yield geminal homo- or hetero-binuclear compounds, which were characterized by IR, NMR and mass spectroscopy.