Stereospecific reactions of the "M(C6F5)2" (M = Pd or Pt) synthons towards cis-dithiolato complexes

DOI: 10.1016/0022-328X(93)80283-H

Source and publish data:

Journal of Organometallic Chemistry p. 137 - 144 (1993)

Update date:2022-08-03

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Authors:

Uson, Rafael

Fornies, Juan

Uson, Miguel A.

Herrero, Santiago

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Article abstract of DOI:10.1016/0022-328X(93)80283-H

Complexes of the general formula cis- (M=Ni, Pd, or Pt; L2=dppm , dppe <1,2-bis(diphenylphosphino)ethane>, or 2PPh3) were synthesized by the reaction (1 : 2) between the corresponding cis- and Tl(SC6F5).When treated with cis- (M=Pd or Pt; THF=OC4H8) they yield geminal homo- or hetero-binuclear compounds, which were characterized by IR, NMR and mass spectroscopy.

Full text of DOI:10.1016/0022-328X(93)80283-H

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