Organometallic compounds of iridium and rhodium. XXXII. (Trimethylsilyl)diazomethyl derivatives of MCl (M=Rh, Ir)

DOI: 10.1016/0022-328X(93)83430-4

Source and publish data:

Journal of Organometallic Chemistry p. C8 - C10 (1993)

Update date:2022-07-29

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Authors:

Dahlenburg, Lutz

Ernst, Markus

Dartiguenave, Michele

Dartiguenave, Yves

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Article abstract of DOI:10.1016/0022-328X(93)83430-4

Treatment of MCl (M=Rh, 1, or Ir, 2) with LiC(N2)SiMe3 in toluene at -78 deg C gave the α-diazoalkyl complexes RhC(N2)SiMe3, 3, and IrC(N2)SiMe3, 4, as air- and light-sensitive but therm

Full text of DOI:10.1016/0022-328X(93)83430-4

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