Tetrahedron p. 3869 - 3878 (1994)
Update date:2022-08-05
Topics:
Chavez, Maria Isabel
Delgado, Guillermo
Stigmasterol, oleanolic acid, morolic acid, hederagenin, and 11α-hydroperoxy-hederagenin were isolated and characterized as the sapogenins present in the aerial parts of the medicinal plant Serjania triquetra (Sapindaceae). The structure of the novel triterpenoid derivative, 11α-hydroperoxy-diacetyl hederagenin, considered as a key biogenetic and chemical intermediate, was confirmed by relay synthesis from diacetyl hederagenin, via bromo-lactonization, dehydrobromination, and oxidation with H2O2. Biogenetic relationships are briefly described.
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Doi:10.1021/om401039z
(2014)Doi:10.1007/BF00811678
(1994)Doi:10.1039/dt9960002309
(1996)Doi:10.1021/ja00089a006
(1994)Doi:10.1016/j.tetasy.2013.12.003
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(1994)