Vinyl Anion Equivalent V. Asymmetric Synthesis of Allylic Alcohols Using Chiral 2-(Trialkylsilyl)ethyl Sulfoxides

DOI: 10.1016/S0040-4020(01)80816-4

Source and publish data:

Tetrahedron p. 1045 - 1062 (1994)

Update date:2022-09-26

Topics:

Authors:

Kusuda, Shinya

Ueno, Yoshio

Toru, Takeshi

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4020(01)80816-4

Both enantiomers of optically pure secondary allylic alcohols can be conveniently prepared by the diastereoselective reaction of the α-sulfinyl carbanion of p-tolyl 2-(trialkylsilyl)ethyl sulfoxides or tert-butyl 2-(trimethylsilyl)ethyl sulfoxide with aldehydes followed by either fluoride-induced desilylsulfinylation or thermal elimination of the sulfinyl group.

Full text of DOI:10.1016/S0040-4020(01)80816-4

Products guided by the article

Product name:(2R,3S)-2-<(R)-p-tolylsulfinyl>-1-(trimethylsilyl)-3-octanol

Cas No:155486-94-5

R&D Labs maybe for 155486-94-5

Changzhou LanXu Chemical Co.,ltd.(expird)

Contact:86-0519-86330911,13656129734,15261186386

Address:Room 524, Depart.Chemical, Changzhou Science and Eductaion town, Jiangsu, China;Factory: Haian Fine Chemical Industry Park,Nantong,Jiangsu,China
Guangzhou Reachin Chemical Co., Ltd

Contact:+86-20-37087379 ext.604

Address:A122C-1, Tianyuan Plaza, 401 Tianyuan Rd., Tianhe, Guangzhou, China
Laohekou Jinghong Chemical Co.,Ltd

Contact:+86-0710-3702747

Address:163.East，Huagong Road，Laohekou
Tengzhou Runlong Fragrance Co., Ltd.

website:http://www.tzrunlong.com/

Contact:--

Address:No. 78, Fushan Road, Biomedical Industrial Park, Dawu Town, Tengzhou, Shandong, 277514 China
Tangshan Wisdom Trading Co.,Ltd

Contact:86 315 2222979

Address:No.41 BeiXinXi Road, Yangguang building 1-1102 , Tangshan, Hebei, China

Relevant to this article

Strategic synthesis of model novolac resins

Doi:10.1016/S0040-4039(00)60747-5
(1994)
Reaction of (bisimido)niobium(V) complexes with organic azides: [3 + 2] cycloaddition and reversible cleavage of β-diketiminato ligands involving nitrene transfer

Doi:10.1021/ja413194z
(2014)
Heat shock protein 70 inhibitors. 2. 2,5′-thiodipyrimidines, 5-(phenylthio)pyrimidines, 2-(pyridin-3-ylthio)pyrimidines, and 3-(phenylthio)pyridines as reversible binders to an allosteric site on heat shock protein 70

Doi:10.1021/jm401552y
(2014)
Potential photoaffinity labels for tubulin. Synthesis and evaluation of diazocyclohexadienone and azide analogs of colchicine, combretastatin, and 3,4,5-trimethoxybiphenyl

Doi:10.1021/jo00094a048
(1994)
Iodine-catalyzed selective synthesis of 2-sulfanylphenols via oxidative aromatization of cyclohexanones and disulfides

Doi:10.1002/adsc.201300493
(2013)
Seven-coordinate molybdenum complexes containing SnRCl2 and phosphorodithioate, X-Ray structure of 2(SnBuCl2)>

Doi:10.1016/0022-328X(93)83409-O
(1993)

Article Doi