Enantioselective synthesis of (-)-conduramine C1 and aminobromocyclitol derivatives

Article abstract of DOI:10.1002/hlca.19940770103

(1S,2R,6R,7R)-4-Phenyl-3-10-dioxa-5-azatricyclo[5.2.1.0^2,6]dec-4-en -9-one ((+)-5) obtained in 6 steps from the Diels-Alder adduct of furan to 1-cyanovinyl (1S)-camphanate ((+)-3) was reduced to the corresponding endo-alcohol (+)-6 the treatmen