Regiocontrol in reductive ring opening of epoxides derived from asymmetrized 2-alkenyl-1,3-propanediols

DOI: 10.1016/S0040-4020(01)85080-8

Source and publish data:

Tetrahedron p. 2219 - 2230 (1994)

Update date:2022-08-05

Topics:

Authors:

Guanti Guanti

Banfi Banfi

Merlo Merlo

Narisano

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Article abstract of DOI:10.1016/S0040-4020(01)85080-8

Homochiral cis epoxides derived from asymmetrized 2 alkenyl-1,3- propanediols are efficiently opened by a variety of hydride donors in the presence of Lewis acids to differently protected triols with a regioselectivity up to 99 : 1.

Full text of DOI:10.1016/S0040-4020(01)85080-8

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