Synthesis p. 276 - 278 (1994)
Update date:2022-08-05
Topics:
Olah
Wang
Neyer
Effective methylthiomethylation of aromatics was achieved by using chloromethyl methyl sulfide/aluminum chloride (MeSCH2Cl:2 AlCl3) as the alkylating agent. Excess aluminum chloride activates the thiocarboxonium ion intermediate by coordinating with sulfur and thus diminishes back donation of 'electron density' into the carbocationic center, rendering it a superelectrophilic methylthiomethylating agent.
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Doi:10.1016/j.tetlet.2013.12.101
(2014)Doi:10.1016/0277-5387(96)00031-9
(1996)Doi:10.1016/j.dyepig.2013.12.019
(2014)Doi:10.1080/15257779408013255
(1994)Doi:10.1021/jo00085a007
(1994)Doi:10.1016/S0040-4020(01)85234-0
(1994)
