A high yield procedure for the Me3SiNTf2-induced carbon-carbon bond-forming reactions of silyl nucleophiles with carbonyl compounds: The importance of addition order and solvent effects

DOI: 10.1055/s-2001-18761

Source and publish data:

Synlett p. 1851 - 1854 (2001)

Update date:2022-08-03

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Authors:

Ishihara

Hiraiwa Hiraiwa

Yamamoto

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Article abstract of DOI:10.1055/s-2001-18761

We demonstrate the efficiency of Me₃SiNTf₂ (0.3-1.0 mol%) as a strong Lewis acid catalyst for the Mukaiyama aldol and Sakurai-Hosomi allylation reactions, and that the slow addition of carbonyl compounds to a solution of acid catalys

Full text of DOI:10.1055/s-2001-18761

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