Tetrahedron Letters p. 3445 - 3448 (1994)
Update date:2022-07-30
Topics:
Samano, Vicente
Robins, Morris J.
Cycloaddition of diazomethane with 3′-deoxy-3′-methylene- and 4′,5′-didehydro-5′-deoxynucleoside derivatives followed by sensitized photochemical extrusion of nitrogen provided the previously unreported 3′- and 4′-spirocyclopropane nucleoside derivatives. Enhancement of the cycloaddition reactions by electron withdrawing benzoyl protecting groups was observed.
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