Tetrahedron Letters p. 745 - 748 (1994)
Update date:2022-07-29
Topics:
Murakami, Teiichi
Minamikawa, Hiroyuki
Hato, Masakatsu
D-erythro-Sphingosine (1) and phytosphingosine (2) have been efficiently synthesized from D-glucosamine by utilizing its whole carbon skeleton and functional groups. In this synthetic route, regioselective alkylation of the epoxy-tosylate 9 was achieved with a copper(I)-catalyzed Grignard reagent to give the key intermediate 10, which was converted to both 1 and 2 via regioselective formation of the iodohydrin 11.
View MoreContact:86-511-85210668 0511-85210668, 85210818, 85210898
Address:Yihai Garden E-902,NO.99 Daxi RD., Zhenjiang Jiiangsu ,China
Contact:+49-4101-3053-0
Address:Waldhofstrasse 14 ,25474 Ellerbek Germany
Contact:
Address:No.89,Xinhua Road, Langfang City,Hebei China
Feiyang Biotechnology Co., Ltd.
Contact:+86-533-7866339
Address:Qilu Chemistry Park, 200m north of Management Community Building of Park
Quzhou Ruiyuan chemical Co., Ltd
Contact:+86-570-3039321/3039361/3039308
Address:18# Huayang Road,Quzhou High-tech Industrial Park, Zhejiang China.
Doi:10.1021/om9806139
(1999)Doi:10.1016/S0040-4039(00)73258-8
(1994)Doi:10.1039/c8nj03339k
(2018)Doi:10.1021/ja00096a057
(1994)Doi:10.1016/j.tetlet.2014.01.041
(2014)Doi:10.1016/j.tetlet.2014.01.105
(2014)
