Synthesis and Characterization of Monochelated Carboxylatopalladium(II) Complexes with Nitrogen-donor Chelating Ligands. Crystal Structures of Diacetato(1,10-phenanthroline)- and Diacetato(2,9-dimethyl-1,10-phenanthroline)-palladium(II)

DOI: 10.1039/DT9940001903

Source and publish data:

Journal of the Chemical Society, Dalton Transactions p. 1903 - 1912 (1994)

Update date:2022-08-02

Topics:

Authors:

Milani, Barbara

Alessio, Enzo

Mestroni, Giovanni

Sommazzi, Anna

Garbassi, Fabio

et al. et al.

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Article abstract of DOI:10.1039/DT9940001903

Two series of monochelated carboxylatopalladium(II) complexes of general formula and 2,9 protons in the phenanthroline series, and those of H^6,6 in the bipyridine one, are excellent probes for the evaluation of the environment of the palladium atom.The crystal structures of , *0.40CH2Cl2 and *0.25CHCl3 (2,9-dmphen=2,9-dimethyl-1,10-phenanthroline) have been determined.The co-ordination geometry around palladium is square planar in all the structures, but significant deviations from the idealized geometry occur in the last two in order to relieve the interligand contacts.These monochelated carboxylatopalladium(II) complexes are active catalysts in carbon monoxide-olefin copolymerization.Some preliminary results on their catalytic activity are also reported.

Full text of DOI:10.1039/DT9940001903

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