Journal of Organometallic Chemistry p. C5 - C7 (1994)
Update date:2022-08-02
Topics:
Zhu, Nianyong
Vahrenkamp, Heinrich
The red closed-shell diamagnetic complex (CO)5Cr-CN-Fe(dppe)Cp (1) is obtained from Naa close to linear Cr-C-N-Fe arrangement, shows no unusual molecular details related to the odd-electron nature of the complex.Spectroscopic data of 2, including a strong IT band at 1130 nm, indicate that 2 is a heterometallic mixed valence complex of class II with a high degree of delocalization.Key words: Chromium; Iron; Carbonyl; Paramagnetism; Phosphorus
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