Generation of 2-Lithio-2-(trimethylsilyl)silacyclopentane and 2-Lithio-2-(phenylthio)silacyclopentane and Their Use for the Synthesis of 1,4-Butanediols and γ-Hydroxy Ketones

DOI: 10.1246/bcsj.67.1694

Source and publish data:

Bulletin of the Chemical Society of Japan p. 1694 - 1700 (1994)

Update date:2022-08-05

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Authors:

Matsumoto, Kozo

Yokoo, Toshiaki

Oshima, Koichiro

Utimoto, Kiitiro

Rahman, Noorsaadah Abd.

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Article abstract of DOI:10.1246/bcsj.67.1694

Treatment of 2-(trimethylsilyl)silacyclopentane with t-butyllithium in THF-HMPA gave 2-lithio-2-(trimethylsilyl)silacyclopentane in good yield.An addition of alkyl iodides to the lithium compound provided 2-alkyl-2-(trimethylsilyl)silacyclopentanes which

Full text of DOI:10.1246/bcsj.67.1694

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