Tetrahedron Letters p. 6143 - 6146 (1994)
Update date:2022-08-03
Topics:
Aitken, R. Alan
Armstrong, David P.
Mesher, Shaun T. E.
Galt, Ronald H. B.
Flash vacuum pyrolysis of a series of chiral 3-benzylthiazolidin-2-one 1,1-dioxides 5, readily prepared from amino acids, results mainly in loss of SO2 to give an alkene and benzyl isocyanate, but a significant minor pathway involves unexpected loss of CO2 and water to give 2-phenylthiazolines 13 and derived thiazoles.
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