A New Approach to the Synthesis of γ-Hydroxy-α,β-unsaturated Macrolides and (-)-Pyrenophorin by Intramolecular C=C Bond Formation with Oxidative Functionalization from ω-alkanal

DOI: 10.1246/cl.1994.1103

Source and publish data:

Chemistry Letters p. 1103 - 1106 (1994)

Update date:2022-08-03

Topics:

Authors:

Nokami, Junzo

Taniguchi, Takuya

Gomyo, Shintaro

Kakihara, Toshio

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Article abstract of DOI:10.1246/cl.1994.1103

The title compounds were prepared via the intramolecular condensation reaction of 12-<α-(p-chlorophenylsulfinyl)acetoxy>tridecanal(or dodecanal) or via the combination of inter- and intramolecular condensation of 5-<α-(p-chlorophenylsulfinyl)acetoxy>hexanal in the presence of piperidine.

Full text of DOI:10.1246/cl.1994.1103

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