The Synthesis of Cyclic Enol Ethers via Molybdenum Alkylidene-Catalyzed Ring-Closing Metathesis

DOI: 10.1021/jo00094a002

Source and publish data:

Journal of Organic Chemistry p. 4029 - 4031 (1994)

Update date:2022-08-02

Topics:

Authors:

Fujimura, Osamu

Fu, Gregory C.

Grubbs, Robert H.

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Article abstract of DOI:10.1021/jo00094a002

An efficient method for the construction of five- and six-membered cyclic vinyl ethers from unsaturated esters using stoichiometric titanium reagents to convert the esters to acyclic olefinic enol ethers which are then transformed to the desired products by catalytic ring-closing olefin metathesis with a molybdenum alkylidene complex is described.

Full text of DOI:10.1021/jo00094a002

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