Tetrahedron Letters p. 1589 - 1592 (1994)
Update date:2022-07-29
Topics:
Alcon, Montserrat
Canas, Marc
Poch, Marta
Moyano, Albert
Pericas, Miquel A.
Riera, Antoni
A new and efficient enantioselective synthesis of allylamines and N-Boc-β-amino acids has been developed.Starting from enantiomerically enriched N-diphenylmethyl-3-amino-1,2-diols, allylamines are easily obtained by a Corey-Hopkins deoxygenative protocol.After a change in the nitrogen protecting group, the resulting N-Boc allylamines are converted into β-amino acids by hydroboration with 9-BBN followed by oxidation with PDC in DMF.
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Doi:10.1016/S0040-4020(01)81758-0
(1994)Doi:10.1016/0008-6215(94)84216-7
(1994)Doi:10.1039/c3dt53366b
(2014)Doi:10.1039/P19960000611
(1996)Doi:10.1246/cl.1994.1071
(1994)Doi:10.1021/ja204255e
(2011)
