Retention of Configuration in the Ritter-type Substitution Reaction of Chiral β-Arylthio Alcohols through the Anchimeric Assistance of the Arylthio Group

DOI: 10.1016/S0040-4020(01)85367-9

Source and publish data:

Tetrahedron p. 8997 - 9008 (1994)

Update date:2022-08-02

Topics:

Authors:

Toshimitsu, Akio

Hirosawa, Chitaru

Tamao, Kohei

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Article abstract of DOI:10.1016/S0040-4020(01)85367-9

In chiral alcohols bearing a phenylthio group at the β carbon atom, the hydroxy group is replaced by nitriles through the anchimeric assistance of the phenylthio group to afford chiral amides with retention of configuration.This stereospecific Ritter-type

Full text of DOI:10.1016/S0040-4020(01)85367-9

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