Synthesis of 7-substituted dehydronoraporphines, with some biogenetic considerations

DOI: 10.1016/S0040-4020(01)89428-X

Source and publish data:

Tetrahedron p. 11257 - 11266 (1994)

Update date:2022-07-30

Topics:

Authors:

Atanes Atanes

Perez Perez

Guitian Guitian

Castedo Castedo

Saa Saa

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Article abstract of DOI:10.1016/S0040-4020(01)89428-X

N-protected 7-methyl-6a,7-dehydronoraporphines were synthesized by the intermolecular benzyne cycloaddition approach. During basic hydrolysis of the N-protecting group, oxidation of these compounds by oxygen led to guacoline and other 7-hydroxy-7-methyl-6,6a-dehydronoraporphines in what may be a biomimetic process.

Full text of DOI:10.1016/S0040-4020(01)89428-X

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